Pradeep Kumar, A. Bera, D. V. S. Muthu, P. M. Shirage, A. Iyo, A. K. Sood
Raman studies on Ca4Al2O5.7Fe2As2 superconductor in the temperature range of 5 K to 300 K, covering the superconducting transition temperature Tc ~ 28.3 K, reveal that the Raman mode at ~ 230 cm-1 shows a sharp jump in frequency by ~ 2 % and linewidth increases by ~ 175 % at To ~ 60 K. Below To, anomalous softening of the mode frequency and a large decrease by ~ 10 cm-1 in the linewidth is observed. These precursor effects at T0 (~ 2Tc) are attributed to significant superconducting fluctuations, possibly enhanced due to reduced dimensionality arising from weaked coupling between the well separated (~ 15 {\AA}) Fe-As layers in the unit cell. A large blue-shift of the mode frequency between 300 K to 60 K (~7%) indicates strong spin-phonon coupling in this superconductor.
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http://arxiv.org/abs/1205.7033
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